Breaking of Icosahedral Symmetry: C60 to C70
نویسندگان
چکیده
We describe the existence and structure of large fullerenes in terms of symmetry breaking of the C60 molecule. Specifically, we describe the existence of C70 in terms of breaking of the icosahedral symmetry of C60 by the insertion into its middle of an additional H2 decagon. The surface of C70 is formed by 12 regular pentagons and 25 regular hexagons. All 105 edges of C70 are of the same length. It should be noted that the structure of the molecules is described in exact coordinates relative to the non-orthogonal icosahedral bases. This symmetry breaking process can be readily applied, and could account for and describe other larger cage cluster fullerene molecules, as well as more complex higher structures such as nanotubes.
منابع مشابه
Optical Absorption in Higher Fullerenes: Effects of Symmetry Reduction
Optical absorption spectra of higher fullerenes (C70 and C76) as well as of C60 are calculated by a tight binding model with a long range Coulomb interaction. A reasonable parameter set gives calculated spectra which are in overall agreement with the experiments of of C60 and C70 in solutions. The variations of the spectral shape are discussed relating with the symmetry reduction going from C60...
متن کاملStimuli-controlled self-assembly of diverse tubular aggregates from one single small monomer
The design and synthesis of new stimuli-responsive hydrogen-bonding monomers that display a diversity of self-assembly pathways is of central importance in supramolecular chemistry. Here we describe the aggregation properties of a simple, intrinsically C2-symmetric enantiopure bicyclic cavity compound bearing a terminally unsubstituted ureidopyrimidinone fragment fused with a pyrrole moiety in ...
متن کاملJahn – Teller instability in cationic boron and carbon buckyballs B 80 + and C 60 + : a comparative study † Jules
using different DFT methods including B3LYP/6-31G(d), VWN/6-31G(d), PBE/TZP and PBE/6-31G(d) shows that, contrary to C60 , which prefers D5d symmetry, the ground state of B80 + adopts S6 point group symmetry. A D3d structure is identified as a saddle point among the S6 minima of B80 . The distortion of D3d to S6 in B80 + is attributed to a superposition of Jahn–Teller and pseudo-Jahn–Teller eff...
متن کاملUnique Crystallization of Fullerenes: Fullerene Flowers
Solution-phase crystallization of fullerene molecules strongly depends on the types of solvent and their ratios because solvent molecules are easily included in the crystal lattice and distort its structure. The C70 (solute)-mesitylene (solvent) system yields crystals with various morphologies and structures, such as cubes, tubes, and imperfect rods. Herein, using C60 and C70 dissolved in mesit...
متن کاملTethered bisadducts of C60 and C70 with addends on a common hexagonal face and a 12-membered hole in the fullerene cage.
The regioselective synthesis of easily isolable pure bismethano derivatives of C60 and C70 with high steric congestion is described using 1,3-dibenzoylpropane bis-p-toluenesulfonyl hydrazone as the addend precursor. When the addition occurs at two [6,6] ring junctions within the same hexagon, bisadducts with mirror symmetry are obtained for both C60 and C70. When the addition occurs at two [5,6...
متن کامل